非均匀多孔介质有效热导率分析

本文采用控制容积法,界面调和平均导热系数值以及图形处理方法对典型非均匀多孔介质硬质聚氨酯泡沫材料的导热过程进行了分析与模拟计算。结果表明:多孔介质的内部结构是影响温度分布和热量传递的主要的因素,其影响程度与骨架和孔隙的导热系数,孔隙的大小和分布有关;计算得到的有效热导率值与文献中实验测量结果吻合较好。本文的研究结果可以推广到更为复杂的非均匀多孔介质的场合,从而可以进一步认识非均匀多孔介质中的导热规律,为工程计算提供更精确的计算方法。     

液态泡沫结构及其稳定性

液态泡沫由大量气泡密集堆积在少量的表面活性剂溶液中形成，是具有高度自组织结构的典型的软物质．文章从泡沫物理学角度简要介绍了液态泡沫的结构特征和稳定性方面的研究．     

Experimental investigation of supersonic radiation propagation in low-density plastic and copper-doped foams

1 Introduction The investigation of supersonic radiation wave transporting in low density foam pro-duced by thermal radiation is of crucial importance in inertial confinement fusion (ICF) research[1]. When the intense radiation flux is incident in the media, first, a supersonic heat wave is formed which propagates into the undisturbed material. In time, due to the increasing mass of heated material, it slows down and is overtaken by a shock wave,thus becoming of the ablative type. Normally, …     

JSOG中水蒸汽含量的模拟计算

氧碘化学激光（简称 COIL）系统中，水是影响激光功率输出的最重要的原因之一。气流中的水不仅对激发态碘原子有严重的猝灭作用，另外对碘分子解离、超音速流动特性也有很坏的负面作用。单重态氧发生器的BHP（Basic Hydrogen Peroxide ）溶液是最主要的水蒸汽源。利用传质模型对射流式单重态氧发生器（简称JSOG）中产生的水蒸汽进行了计算，所得的数值结果与实验测量结果基本相符。根据模拟结果，对发生器的设计及实验条件进行了优化。     

Bioprocess for solubilization of rock phosphate on starch based medium by Paecilomyces marquandii immobilized on polyurethane foam

Paecilomyces marquandii, a phosphate-solubilizing, starch-utilizing filamentous fungus, was immobilized on polyurethane foam (PUF). The immobilized fungus was applied in a repeated batch (six batches) fermentation process to solubilize Hirapur rock phosphate. The fungus was immobilized on PUF cubes and was used for phosphate solubilization in shake flask repeated batch cultivations. The fungus was also immobilized on PUF sheet and utilized in an airlift bioreactor in a repeated batch process. Maximum soluble phosphate (370 μg/ml) was recorded after third batch with 8 g rock phosphate/l. After 12 days of fermentation, a total production of 1,643 μg phosphate/ml was achieved.     

Quantum-Gravitational Diffusion and Stochastic Fluctuations in the Velocity of Light

We argue that quantum-gravitational fluctuations in the space-time background give the vacuum non-trivial optical properties that include diffusion and consequent uncertainties in the arrival times of photons, causing stochastic fluctuations in the velocity of light in vacuo. Our proposal is motivated within a Liouville string formulation of quantum gravity that also suggests a frequency-dependent refractive index of the particle vacuum. We construct an explicit realization by treating photon propagation through quantum excitations of D-brane fluctuations in the space-time foam. These are described by higher-genus string effects, that lead to stochastic fluctuations in couplings, and hence in the velocity of light. We discuss the possibilities of constraining or measuring photon diffusion in vacuo via -ray observations of distant astrophysical sources.     

New type of spherical pore Al alloy foam with low porosity and high strength

The Ultra Light Metal Structure with variouskinds of pores (open, close) realizes the lightness andmultifunction of structural material. The functionsinclude lightness (ρ < 1), high specific strength, highenergy absorption, sound insulation, heat insulationand electromagnetism shield. It is one of the hotspotsin material research nowadays[1— . The requirements 6]of high speed movement and high technology make Alalloy foam, which has higher specific st…     

Lattice gas simulations of two-dimensional liquid foams

Liquid foam is a dense random packing of gas bubbles in a small amount of immiscible liquid containing surfactants. The liquid within the Plateau borders, although small in volume, causes considerable difficulties to investigations of the physical properties of foams, and the situation becomes even more complicated if the flow of the liquid through the foam is considered too. Here we propose a fresh approach to tackling these issues by introducing a discrete two-dimensional hybrid lattice gas model of liquid foams. While lattice gas models have been used to model two-phase liquids in the past, their application to the study of liquid foams is novel and proves promising. We represent bubble surfaces by a finite number of nodes, and model the surrounding liquid as a lattice gas (with a finite number of liquid particles). The gas in the bubbles is treated as an ideal gas at constant temperature. The model is tested by choosing an arbitrarily shaped bubble that evolves into a circular shape in agreement with Laplaces law. The model is then employed to simulate periodic ordered and disordered dry and wet foams. Since our model is specifically designed to handle wet foams up to a critical liquid fraction of 0.16 (void fraction of random packing of disks), we are able to compute the variation in coordination number (average number of neighbours of a bubble) over the whole range of liquid fractions, and we find it to be a linear function of the shear modulus.This paper was presented at the first Annual European Rheology Conference (AERC) held in Guimarães, Portugal, 11–13 September 2003.     

Preparation of novel ion exchange polyurethane foam and its application for separation and determination of palladium in environmental samples

The new strong anion exchanger (PUFIX) from polyurethane foam was prepared by coupling of the primary amine of the foam matrix with ethyl iodide. PUFIX was characterized using different tools (IR spectra, elemental analysis, density and thermal analysis). The sorption properties of the new anion exchanger (PUFIX) and chromatographic behaviour for separation and determination of palladium(II) ions at low concentrations from aqueous iodide or thiocyanate media were investigated by a batch and dynamic processes. The maximum sorption of Pd(II) was in the pH range of 0.3–2. The kinetics of sorption of the Pd(II) by the PUFIX was found to be fast with average values of half-life of sorption (t_1/2) of 3.32 min. The variation of the sorption of Pd(II) with temperature gives average values of ΔH, ΔS, ΔG and ΔE to be −38.3 kJ mol⁻¹, −100.7 J K⁻¹ mol⁻¹, −8.3 and 11.8 kJ mol⁻¹, respectively. The sorption capacity of PUFIX was 1.69 mmol g⁻¹ for Pd(II), preconcentration factors of values ≈250 and the recovery 99–100% were achieved (R.S.D. ≈ 1.24%). The lower detection limit, 1.28 ng mL⁻¹ was evaluated using spectrophotometric method (R.S.D. ≈ 2.46%).     

多壁碳纳米管-炭复合泡沫材料的制备和吸附性能

通过在聚氨酯泡沫模板中沉积多壁碳纳米管，用炭的预制体酚醛树酯将碳纳米管粘接固定在一起，经过高温碳化过程制备了碳纳米管-炭复合泡沫材料。红外光谱结果表明利用浓硫酸和浓硝酸的混合溶液处理可以使复合泡沫表面活化形成羧基和羟基，从而使复合泡沫具备较强的分子吸附能力。扫描电镜和氮吸附实验表明这种复合泡沫同时具备大孔和介孔，大孔能够满足流体自由流动的通畅性，介孔可以满足中分子的吸附需要。对标定物维生素B12的吸附实验证明这种复合泡沫对中分子量的生化分子具有有效的吸附能力。这种宏观尺寸的泡沫材料与传统的颗粒状活性炭相比具有简化工艺，提高吸附效率的应用潜力。